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23 Feb 2015 Ensemble averaging of molecular states is fundamental for the experimental determination of thermodynamic quantities. A special case occurs 

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Raoult's law (/ ˈ r ɑː uː l z/ law) is a law of thermodynamics established by French chemist François-Marie Raoult in 1887. It states that the partial pressure of each component of an ideal mixture of liquids is equal to the vapour pressure…

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Physical Chemistry Physical chemistry is the branch of chemistry that establishes and develops the principles of Chemistry in terms of the underlying concepts of Physics Physical Chemistry Main book: Atkins 3 which appear in these systems that have the same macroscopic description, molecular fluctuations are used. These fluctuations must be small.